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A study on phenol migration by coupling the liquid membrane in the ionic liquid

机译:a study on phenol migration by coupling the liquid membrane in the ionic liquid

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摘要

The environmental pollution of phenol is primarily taken as a result of wastewater discharged from some special chemical plants. It is the common pollutant to be controlled in industrial wastewater, and therefore, how to effectively minimize its environmental pollution by the phenolic pollutants treatment and recovery becomes an important subject. This paper aims to make a study on the support liquid membrane separation from phenolic wastewater in hydrated environment. The process of separation is conducted with hydrophobic ionic liquid 1-butyl-3-methylimidazole hexafluorophosphate [BMIM]PF6 prepared by the microwave synthesis method based on fundamental solvent extraction research and applied to the inner coupling liquid membrane system. as the purpose is to migrate phenol in the simulated wastewater and survey the temperature, stirring speed, feed liquid phase acidity, initial concentration and NaOH concentration in the stripping phase influence on the phenol migration to obtain the preferred condition for migration. The said condition is as follows: The temperature of 300 K, the stirring speed ranging from 350 to 400 rpm, the feed liquid phase pH of 3.65, and NaOH concentration of 0.8 mol/L in the stripping phase. In the system, phenol is approximated to 100% in migration rate and the ionic liquid may be recycled for several times. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
机译:苯酚对环境的污染主要来自某些特殊化工厂排放的废水。它是工业废水中常见的污染物,因此,如何通过酚类污染物的处理和回收有效地减少其对环境的污染成为重要课题。本文旨在对水合环境中酚类废水中支持液膜的分离进行研究。分离过程是通过基于基础溶剂萃取研究的微波合成方法制备的疏水离子液体1-丁基-3-甲基咪唑六氟磷酸盐[BMIM] PF6进行的,并将其应用于内耦合液膜系统。目的是为了在模拟废水中迁移苯酚,并测量温度,搅拌速度,进料液相酸度,汽提阶段的初始浓度和NaOH浓度对苯酚迁移的影响,以获得迁移的优选条件。所述条件如下:温度为300 K,搅拌速度为350-400 rpm,汽提阶段的进料液相pH为3.65,NaOH浓度为0.8 mol / L。在该系统中,苯酚的迁移率大约为100%,离子液体可以循环使用几次。 (C)2016氢能出版物有限公司。由Elsevier Ltd.出版。保留所有权利。

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  • 作者

    Lu S. B.; Pei, L.;

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  • 年度 2016
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  • 原文格式 PDF
  • 正文语种 英语
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